Isolation of cubic Si₃P₄ in the form of nanocrystals

• Polina K. Nikiforova,
• Sergei S. Bubenov,
• Vadim B. Platonov,
• Andrey S. Kumskov,
• Nikolay N. Kononov,
• Tatyana A. Kuznetsova and
• Sergey G. Dorofeev

Beilstein J. Nanotechnol. 2023, 14, 971–979, doi:10.3762/bjnano.14.80

• ] (the benefit of the gaseous etching is that the particles remain dry, resulting in a lower oxidation rate [45]). One of the samples had also been pre-annealed in vacuum at 900 °C for 6 h before the etching step to estimate the influence of an amorphous surface layer of the NPs on Si3P4 phase formation

Cross-sectional Kelvin probe force microscopy on III–V epitaxial multilayer stacks: challenges and perspectives

• Mattia da Lisca,
• José Alvarez,
• James P. Connolly,
• Nicolas Vaissiere,
• Karim Mekhazni,
• Jean Decobert and
• Jean-Paul Kleider

Beilstein J. Nanotechnol. 2023, 14, 725–737, doi:10.3762/bjnano.14.59

• sample was then placed in 1% HF solution for 30 s to etch the top oxide layer. This step was followed by a rinsing with deionized water and drying in air. This procedure was necessary for an optimal KPFM analysis since the presence of a native oxide surface layer on top can lead to the measurement of a

• section was used. KPFM is a surface technique; therefore, KPFM measurements are strongly influenced by the presence of surface defects. In order to provide a quantitative analysis of the experimental results, KELSCAN allows for the introduction of defects in a surface layer of arbitrary depth. The model

Electrical and optical enhancement of ITO/Mo bilayer thin films via laser annealing

• Abdelbaki Hacini,
• Ahmad Hadi Ali,
• Nurul Nadia Adnan and
• Nafarizal Nayan

Beilstein J. Nanotechnol. 2022, 13, 1589–1595, doi:10.3762/bjnano.13.133

• annealing, a laser beam irradiates the surface layer of the thin film without causing damage. The temperature increases quickly during the process within a short period [24][27]. The laser beam must have a uniform intensity with asymmetrical distribution to obtain surfaces of good morphology with low

Studies of probe tip materials by atomic force microscopy: a review

• Ke Xu and
• Yuzhe Liu

Beilstein J. Nanotechnol. 2022, 13, 1256–1267, doi:10.3762/bjnano.13.104

• extract vertically aligned carbon nanotubes based on the surface layer of the substrate. This method extracts single-walled carbon nanotubes (SWNTs) on the substrate surface based on the observation of micromachined tips by first fabricating vertically aligned SWNT substrates with isolation effects

Effects of focused electron beam irradiation parameters on direct nanostructure formation on Ag surfaces

• Jānis Sniķeris,
• Vjačeslavs Gerbreders,
• Andrejs Bulanovs and
• Ēriks Sļedevskis

Beilstein J. Nanotechnol. 2022, 13, 1004–1010, doi:10.3762/bjnano.13.87

• surface layer of twinned B19’ martensite being pulled up along the growth of the nanodot. After heating the Ni40Ti60 surface to 100 °C, where the shape memory effect is expected to be activated due to the phase transition from B19’ martensite to B2 austenite, the surface surrounding the nanodot was found

Interaction between honeybee mandibles and propolis

• Leonie Saccardi,
• Franz Brümmer,
• Jonas Schiebl,
• Oliver Schwarz,
• Alexander Kovalev and
• Stanislav Gorb

Beilstein J. Nanotechnol. 2022, 13, 958–974, doi:10.3762/bjnano.13.84

• channel between the ledge and central ridge (Figure 8B). In the flat area the layer measured 1.56 ± 1.04 µm in thickness (Figure 8C–F). Close to the unstructured sharp edge the layer was thin (0.053 ± 0.015 µm) (Figure 8G,H). In some places the contact angle of the surface layer on the cuticle could be

• studied in regular SEM. Different washing treatments were applied in order to remove the surface layer from the mandibles. Examination in the SEM showed that on mandibles washed with water the residues of the substance covering the surface were still present to a similar extent as on untreated mandibles

Investigation of electron-induced cross-linking of self-assembled monolayers by scanning tunneling microscopy

• Patrick Stohmann,
• Sascha Koch,
• Yang Yang,
• Christopher David Kaiser,
• Julian Ehrens,
• Jürgen Schnack,
• Niklas Biere,
• Dario Anselmetti,
• Armin Gölzhäuser and
• Xianghui Zhang

Beilstein J. Nanotechnol. 2022, 13, 462–471, doi:10.3762/bjnano.13.39

• in a less dense but more ordered structure over a large area with very few defects. During the self-assembly process, gold adatoms are ejected from the surface layer due to the relaxation of the herringbone reconstruction [68]. Several gold adatom islands, which would build up if the density of

A comprehensive review on electrospun nanohybrid membranes for wastewater treatment

• Senuri Kumarage,
• Imalka Munaweera and
• Nilwala Kottegoda

Beilstein J. Nanotechnol. 2022, 13, 137–159, doi:10.3762/bjnano.13.10

• membrane was then modified by a thin surface layer of polyamide (PA), which was obtained from interfacial polymerization of m-phenylenediamine (MPD) and 1,3,5-benzenetricarbonyl chloride (TMC). The membrane was used to separate soybean oil from distilled water. The content of NaOH and the thin polyamide

Chemical vapor deposition of germanium-rich CrGe_x nanowires

• Vladislav Dřínek,
• Stanislav Tiagulskyi,
• Roman Yatskiv,
• Jan Grym,
• Radek Fajgar,
• Věra Jandová,
• Martin Koštejn and
• Jaroslav Kupčík

Beilstein J. Nanotechnol. 2021, 12, 1365–1371, doi:10.3762/bjnano.12.100

• significantly higher than the one obtained by EDX, namely 1:(8–12), which could be explained by chromium enrichment in the superficial surface layer of the deposit after its exposure to air. Elemental analysis obtained from the coating of individual nanowires showed this ratio to be in the range of 1:(8–10

An overview of microneedle applications, materials, and fabrication methods

• Zahra Faraji Rad,
• Philip D. Prewett and
• Graham J. Davies

Beilstein J. Nanotechnol. 2021, 12, 1034–1046, doi:10.3762/bjnano.12.77

• -opened, conical, bevelled tip, (3) material selection, (4) fabrication feasibility, (5) application, (6) layout of the arrays, (7) density, (8) total number of microneedles, and (9) surface layer state (e.g., hydrophobicity). In addition, microneedles are defined according to their array density, length

Physical constraints lead to parallel evolution of micro- and nanostructures of animal adhesive pads: a review

• Thies H. Büscher and
• Stanislav N. Gorb

Beilstein J. Nanotechnol. 2021, 12, 725–743, doi:10.3762/bjnano.12.57

• convergent results. In the next subsections we discuss the following functional principles: (1) Adaptation to fractal substrate surfaces due to hierarchical organization and thin surface layer, (2) micro- and nanostructural surface pattern and contact splitting, (3) pad material (structure) that is soft

Prediction of Co and Ru nanocluster morphology on 2D MoS₂ from interaction energies

• Cara-Lena Nies and
• Michael Nolan

Beilstein J. Nanotechnol. 2021, 12, 704–724, doi:10.3762/bjnano.12.56

• , (b) ML rearrangements including incorporation of metal atoms into the S layer and (c) formation of metal–S clusters. Incorporation of adatoms into the surface layer is known to increase the metal–substrate interaction, as is the lack of metal–metal bonds [48]. A gain in the metal–substrate

Electromigration-induced formation of percolating adsorbate islands during condensation from the gaseous phase: a computational study

• Alina V. Dvornichenko,
• Vasyl O. Kharchenko and
• Dmitrii O. Kharchenko

Beilstein J. Nanotechnol. 2021, 12, 694–703, doi:10.3762/bjnano.12.55

• snapshots in Figure 3b). These islands diffuse and interact. At large time scales the dispersion attains a constant non-zero value and the surface layer is characterized by stationary surface patterns, that is, separated adsorbate islands on the substrate (top panel in Figure 3b) or separated holes inside

• the adsorbate matrix (bottom panel in Figure 3b). It follows, that a variation in the adsorption rate α and/or the rate of the transference reactions k∥ can lead to different morphology of the surface layer. In Figure 4 we show the stability diagram at ε = 4 and the dependence αm(k∥), which was

Interface interaction of transition metal phthalocyanines with strontium titanate (100)

• Reimer Karstens,
• Thomas Chassé and
• Heiko Peisert

Beilstein J. Nanotechnol. 2021, 12, 485–496, doi:10.3762/bjnano.12.39

• via the nitrogen atoms were observed [47][50]. In contrast, interactions via the central metal atom are hardly observed on rutile TiO2 [50]. A reason for the different behavior of rutile and STO(100) surfaces might be the different composition of the outermost surface layer. For rutile TiO2 surfaces

Boosting of photocatalytic hydrogen evolution via chlorine doping of polymeric carbon nitride

• Malgorzata Aleksandrzak,
• Michalina Kijaczko,
• Wojciech Kukulka,
• Daria Baranowska,
• Martyna Baca,
• Beata Zielinska and
• Ewa Mijowska

Beilstein J. Nanotechnol. 2021, 12, 473–484, doi:10.3762/bjnano.12.38

• , nitrogen, and oxygen. Additionally, the chlorine signal was detected in the doped sample. The atomic concentration of the elements was calculated assuming a homogeneous distribution in the analyzed surface layer and it is given in Table 1. The obtained results show that melamine polycondensation with 2

Nickel nanoparticle-decorated reduced graphene oxide/WO₃ nanocomposite – a promising candidate for gas sensing

• Ilka Simon,
• Alexandr Savitsky,
• Rolf Mülhaupt,
• Vladimir Pankov and
• Christoph Janiak

Beilstein J. Nanotechnol. 2021, 12, 343–353, doi:10.3762/bjnano.12.28

• (approximately 25 nm in size), which are located in the partly formed agglomerates in the initial composite, is possible (Figure 2, right). The increase in the Curie temperature with the size of nanoparticles is known [63][64]. It is explained by a decrease in the fraction of the nickel particle surface layer

Gold(I) N-heterocyclic carbene precursors for focused electron beam-induced deposition

• Cristiano Glessi,
• Aya Mahgoub,
• Cornelis W. Hagen and
• Mats Tilset

Beilstein J. Nanotechnol. 2021, 12, 257–269, doi:10.3762/bjnano.12.21

• precursors under electron irradiation [53]. EDX analyses of the deposits show the presence of silicon and oxygen, which are not present in the precursor molecules. Their presence is likely to come from the silicon substrate with its native oxide surface layer. The triazole-based compound 6 is the best

The role of gold atom concentration in the formation of Cu–Au nanoparticles from the gas phase

• Yuri Ya. Gafner,
• Svetlana L. Gafner,
• Darya A. Ryzkova and
• Andrey V. Nomoev

Beilstein J. Nanotechnol. 2021, 12, 72–81, doi:10.3762/bjnano.12.6

• displacement of Au atoms into the surface layer. Moreover, the rate of segregation increased with temperature, which was experimentally confirmed [24]. This effect is a direct consequence of the different binding energies of gold and copper atoms (i.e., with these nanoparticle sizes, the binding energy of

Influence of the magnetic nanoparticle coating on the magnetic relaxation time

• Mihaela Osaci and
• Matteo Cacciola

Beilstein J. Nanotechnol. 2020, 11, 1207–1216, doi:10.3762/bjnano.11.105

• distribution of the grain size. Each nanoparticle is composed of a magnetic core and a nonmagnetic surface layer of stabilizing surfactant. The system temperature is considered to be constant. To simulate the self-organization of the colloidal magnetic nanoparticles we used the Langevin dynamics stochastic

• or by the density of the polymer surface layer. Figure 3 and Figure 4 show the average value of the effective magnetic relaxation time versus the thickness of the nanoparticle coating layer for low and high values of the polymer surface density, respectively. For low values of the polymer surface

• thickness of the surfactant coating layer and the density of the polymer surface layer influence both the Néel relaxation time and the effective magnetic relaxation time in a system consisting of magnetic nanoparticles suspended in a liquid matrix. To simulate the self-organization of the colloidal

Comparison of fresh and aged lithium iron phosphate cathodes using a tailored electrochemical strain microscopy technique

• Matthias Simolka,
• Hanno Kaess and
• Kaspar Andreas Friedrich

Beilstein J. Nanotechnol. 2020, 11, 583–596, doi:10.3762/bjnano.11.46

• capacity loss from first charge to first discharge is attributed to surface layer generation (anode: solid electrolyte interface, SEI; cathode: solid permeable interface, SPI) on both electrodes, since they were rinsed before the full-cell assembly. After the first cycle, the capacity stays constant (not

• diffusion coefficient due to ageing. However, they correlate this to the surface layer build up on the cathodes and not to any degradation of the cathode material itself [6]. Regarding the discrepancy between experimentally and theoretically derived diffusion coefficients, Malik et al. [65] pointed out that

Formation of nanoripples on ZnO flat substrates and nanorods by gas cluster ion bombardment

• Xiaomei Zeng,
• Vasiliy Pelenovich,
• Bin Xing,
• Rakhim Rakhimov,
• Wenbin Zuo,
• Alexander Tolstogouzov,
• Chuansheng Liu,
• Dejun Fu and
• Xiangheng Xiao

Beilstein J. Nanotechnol. 2020, 11, 383–390, doi:10.3762/bjnano.11.29

• al. predicting a remarkably defect-free ripple formation on the plane surface by ion bombardment of a binary material should also be noted [10]. In this theory, the composition change of the surface layer by the ion bombardment is discussed and a defect-free ripple formation of an elemental material

Nanosecond resistive switching in Ag/AgI/PtIr nanojunctions

• Botond Sánta,
• Dániel Molnár,
• Patrick Haiber,
• Agnes Gubicza,
• Edit Szilágyi,
• Zsolt Zolnai,
• András Halbritter and
• Miklós Csontos

Beilstein J. Nanotechnol. 2020, 11, 92–100, doi:10.3762/bjnano.11.9

• directly followed by the onset of stable hysteretic traces without the need of any further dedicated electroforming procedure. We argue, that the indention of the tip to the surface layer reduces the effective thickness of the dielectric layer resulting in the down-scaling of the electroforming voltage to

pH-Controlled fluorescence switching in water-dispersed polymer brushes grafted to modified boron nitride nanotubes for cellular imaging

• Saban Kalay,
• Yurij Stetsyshyn,
• Volodymyr Donchak,
• Khrystyna Harhay,
• Ostap Lishchynskyi,
• Halyna Ohar,
• Yuriy Panchenko,
• Stanislav Voronov and
• Mustafa Çulha

Beilstein J. Nanotechnol. 2019, 10, 2428–2439, doi:10.3762/bjnano.10.233

• under acidic conditions [42]. In our previous work [12], we have reported a two-step method for preparation of a responsive surface layer on oligoperoxide-functionalized BNNTs, where amino groups on BNNTs form at the ends and defects. Additional amine groups can be easily introduced with ammonia plasma

Nitrogen-vacancy centers in diamond for nanoscale magnetic resonance imaging applications

• Alberto Boretti,
• Lorenzo Rosa,
• Jonathan Blackledge and
• Stefania Castelletto

Beilstein J. Nanotechnol. 2019, 10, 2128–2151, doi:10.3762/bjnano.10.207

Magnetic properties of biofunctionalized iron oxide nanoparticles as magnetic resonance imaging contrast agents

• Natalia E. Gervits,
• Andrey A. Gippius,
• Alexey V. Tkachev,
• Evgeniy I. Demikhov,
• Sergey S. Starchikov,
• Igor S. Lyubutin,
• Alexander L. Vasiliev,
• Vladimir P. Chekhonin,
• Maxim A. Abakumov,
• Alevtina S. Semkina and
• Alexander G. Mazhuga

Beilstein J. Nanotechnol. 2019, 10, 1964–1972, doi:10.3762/bjnano.10.193

• allowed us to determine the relative amount of iron located in the core and the surface layer of the nanoparticles. The obtained results are important for understanding the structural and magnetic properties of iron oxide nanoparticles used as T2 contrast agents for MRI. Keywords: iron oxides; Mössbauer

• frequency region of the NMR spectrum, which most likely originates from iron atoms located in the surface layer of the particles. This assumption is indirectly confirmed by the absence of such a shoulder in the spectra of similar particles of larger size, which thus have a smaller ratio of surface/core